Coating compostions for metal substrates based on ethylenetetrafluoroethylene copolymers

ABSTRACT

Coating compositions for metal substrates comprising a mixture of ethylene-tetrafluoroethylene copolymers, said mixture including an ethylene-tetrafluoroethylene copolymer having 50-60 mol % of tetrafluoroethylene with a melting point from about 250*C to about 315*C and an ethylene-tetrafluoroethylene copolymer having more than 60 or less than 45 mol % of tetrafluoroethylene with a melting point from about 180* to about 285*C and a latent solvent. The composition may optionally include a fluidizing solvent and various pigments, inert fillers and other additives.

United States Patent [191 Mattiussi et a].

[ Sept. 16, 1975 COATING COMPOSTIONS FOR NIETAL SUBSTRATES BASED ON ETHYLENETETRAFLUOROETHYLENE COPOLYMERS [75] Inventors: Andrea Mattiussi; Mario Modena,

both of Bollate, Italy [73] Assignee: Montecatini Edison S.p.A., Milan,

Italy [22] Filed: June 25, 1973 21 App]. No.: 373,163

[30] Foreign Application Priority Data June 28, 1972 Italy 26325/72 [52] U.S. CI 260/897 C; 117/132 CF; 260/30.2; 260/30.4 R; 260/30.6; 260/30.8; 260/31 8 M; 260/31.6; 260/324; 260/32.6 R; 260/32.8 R;

260/33.2 R; 260/33.4 F; 260/336 F; 260/42.27

[5 I] Int. Cl. C08f 29/22 [58] Field of Search 260/897 C, 900

[56] References Cited UNITED STATES PATENTS 2,412,960 12/1946 Berry 260/32 9/1964 Boyer 264/211 8/1967 Larsen 260/897 FOREIGN PATENTS OR APPLICATIONS 1,166,020 10/1969 United Kingdom 260/87.5 A

Primary Examiner-J0hn C. Bleutge Assistant ExaminerC. J. Seccuro Attorney, Agent, or FirmHubbell, Cohen and Stiefel 57 ABSTRACT 9 Claims, No Drawings COATING COMPOSTIONS FOR IVIETAL SUBSTRATES BASED ON ETHYLENETETRAFLUOROETHYLENE COPOLYMERS CROSS REFERENCE TO RELATED APPLICATIONS None.

BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to coating compositions based on ethylene-tetrafluoroethylene, (hereinafter referred to as E-TF E) copolymers, which capable of forming films that are adhere perfectly to metal surfaces of different types, even after aging.

2. Prior Art It is well known that E-TFE copolymers have certain desirable physical and chemical characteristics, such as substantial inertia to chemical reactants in general, good thermal stability and excellent dielectric properties.

In U.S. patent application Ser. No. 142,357, now abandoned, coating compositions based on fluorinated polymeric materials consisting of E-TFE copolymers containing from 50 to 70 mol of chemically combined tetrafluoroethylene are disclosed.

In fact, it has been found that those coating compositions are capable of yielding films that adhere perfectly to metal surfaces of different types, even after aging.

However, it was also found that the filming properties of those compositions are not quite as good as desired. In fact, in order to obtain complete and reproducible filming of the compositions containing copolymers of such a composition (50-60 mol of tetrafluoroethylene) as to have a melting point near the maximum value typical of this class of polymeric materials, it is necessary to effect a thermal baking treatment of the coated metal surface at temperatures above 300C and for baking times often exceeding two or three minutes.

This requirement for extended thermal baking represents a considerable limitation in the use and a serious disadvantage for such coating compositions. This is especially so when one considers that the required coating conditions greatly exceed the conditions attainable in the standard machines that are commercially used for the continuous coating of metal substrates. Thus, these machines cannot be used with the above described polymeric compositions.

SUMMARY OF THE INVENTION tions based on E-TFE copolymers which contain as the Y fluorinated polymeric material, a mixture of:

a. at least one E-TFE copolymer having a melting point from about 250 to about 315C and containing from 50 to 60 mol of chemically combined tetrafluoroethylene, and

b. at least one E-TFE copolymer having a melting point from about 180 to about 285C and containing more than 60 mol or less than 45 mol of chemically combined tetrafluoroethylene.

Preferably, the higher melting E-TFE copolymers (a) contain from 52 to 58 mol of chemically combined tetrafluoroethylene, while the lower melting copolymers (b) contain from 35 to 45 mol or from 60 to mol of chemically combined tetrafluoroethylene.

As a matter of fact, it has surprisingly been found that with polymeric compositions of the type hereinabove described, it is possible to effect complete filming with maximum of reproducibility, at temperatures between about 260 and 300C, and with baking times between 1 and 2 minutes. These conditions are quite typical for the equipment used on a commercial scale for the continuous industrial coating of metal substrates with coating compositions based on polymeric materials in general.

In the compositions according to this invention, the ratio between the above-described copolymers (a) and (b) may vary within rather wide limits, depending on the type of coating to be obtained, on the type of substrate to be coated and on the conditions under which the coating is to be performed.

When copolymer (b) contains less than 45 mol of I tetrafluoroethylene, it is preferred to use it in amounts below 50% by weight of the total weight of (a) (b), in order not to diminish the excellent resistance of the coating film against chemical atmospheric agents which results from the presence of copolymer (a).

The mixture of copolymers (a) (b), which is to be used as the polymeric component of the compositions according to this invention may be prepared either by mixing the two copolymers together in the form of powders thereof, or by mixing aqueous dispersions of the two copolymers.

The polymeric compositions according to this invention comprise, in addition to the above specified admixture of copolymers (a) and (b), at least one latent solvent and, optionally, at least one fluidizing solvent, at least one inert pigment and other additives of the type well known to those skilled in the art of coating compositions.

As used herein, the term latent solvent is intended to mean those organic compounds capable of exerting a solvent action on the E-TFE copolymers at high temperatures and generally above C, thereby allowing one to obtain a homogeneous copolymer film after the elimination of the latent solvent.

Examples of such latent solvents are the alkyl and alkoxyl (C C esters of aliphatic and aromatic monoand polycarboxylic acids, such as dimethyladipate, dimethylsebacate, diethylsuccinate, dimethylphthalate, dibutylphthalate, diisobutylphthalate, dibutyladipate, dibutylsebacate, 2- methoxyethylacetate, 2-butyloxyethylacetate,

dimethoxyethylphthalate, and the like; glycol-ethers and glycol-esters such as diethyleneglycolmonomethyletheracetate, diethylene-glycolmonobutylethereacetate, and the like; cyclic ethers such as dioxane, tetrahydrofuran, and the like; alkylenecarbonates such as ethylenecarbonate, propylene carbonate, and the like; lactones such as butyrolactone, valerolactone, and the like; nitroalkanes such as nitromethane, nitroethane, l-nitropropane, 2-nitropropane, and the like; sulfones such as ,cyclobutadiensulfone, tetramethylensulfone, dimethylsulfolane, hexamethylensult'one, and the like; nitriles such as dicyanobutene, adiponitrile, and

the like; amides such as N, N-dimethylformamide, N, N-diethylformamide, N, N-dimethylacetamide and the like; pyrrolidone and alkyl derivatives thereof such as N-methyl-Z-pyrrolidone, N-ethyl-Z-pyrrolidone, and the like; organic phosphates and phosphites such as diethylphosphate, tricresylphosphate, and the like.

These compounds may be used either alone or in admixture with each other.

A preferred group of latent solvents are the high boiling esters such as dibutylphthalate, diisooctylphthalate, dimethylphthalate, dibutyladipate, dibutylsebacate, tricresylphosphate and other similar compounds.

As used herein, the term fluidizing solvent" is intended to mean organic compounds which are more volatile than the latent solvents and which are capable of imparting to the copolymer-latent solvent system a viscosity such as will allow the spreading of the resulting composition on substrates of various types following well known techniques and using standard equip ment, such as for instance dipping, spraying, rollerspreading, the use of spiral film-spreaders, blade-filmspreaders and the like.

Examples for these fluidizing solvents are ketones such as methylethylketone, methylisobutylketone, ethylamylketone, acetone, diaceton-alcohol, cyclohexanone, isophorone, mesityl oxide, and the like; aromatic hydrocarbons such as benzene, toluene, xylenes, and the like; low boiling esters such as ethyl acetate, amyl butyrate, and the like; low boiling glycols such as ethylene and propylene glycol, derivatives thereof and other similar compounds.

These compounds may be used either alone or in admixture with each other.

The pigments and inert fillers optionally used in the coating compositions according to the invention may be selected from a large group of organic and inorganic thermally resistant substances of the type well known to those skilled in the art of coating compositions.

In the case of coating compositions of a white color, the preferred pigment is titanium dioxide.

The nature of the various components, as well as the ratios by weight between the E-TFE copolymers/latent solvent/fluidizing solvent/pigment in the coating compositions of the invention vary over wide limits depending on the ultimate use for which they are intended, and more particularly they depend on the type of substrate to be coated, on the spreading conditions and on the thermal treatment of the coating composition itself.

Particularly advantageous results may be obtained by using coating compositions comprising:

E-TFE copolymers (in powder form) 100 pars by weight latent solvent 100-500 parts by weight fluidizing solvent O-50 parts by weight pigment -150 parts by weight In addition to the above mentioned components, the compositions according to the invention may also include minor amounts of other additives such as surfactants, stabilizers, anti-oxidants, UV absorbers and the like.

For special applications the fluidizing solvent may be omitted.

DESCRIPTION OF THE PREFERRED EMBODIMENTS The coating compositions according to the invention may be prepared and applied to substrates according to techniques well known in the art.

Thus, according to a preferred laboratory method, the coating compositions according to this invention are prepared by a process that comprises in order, the following operational steps:

1. Introducing into a quick mixer the entire quantity of latent solvent; although in the case of a pigment containing composition, only a portion of the latent solvent should be introduced.

2. Adding about one-third of the copolymer mixture in powder form.

3. When a pigment is to be included in the composition, adding same with the remaining portion of the latent solvent.

4. Stirring the thus obtained mixture, for about 23 minutes at high velocity.

5. Adding the remaining two-thirds of the powdered copolymer mixture in subsequent portions and vigorously stirring the mixture for 23 minutes between each addition.

6. Subjecting the thus obtained mixture to a final stirring for 3-4 minutes.

7. Introducing suitable portions of the fluidizing solvent during the mixing step, in order to conveniently adjust the viscosity of the system.

8. Degassing the obtained dispersion of the copolymers at reduced pressure.

This dispersion is then ready for use as a varnish that may be applied on different types of metal substrates such as, for example, steel, soft steel, phosphatized soft steel, galvanized sheet iron, aluminum, chromated aluminum and the like.

The methods and equipment most'commonly used for applying the present coating compositions to a substrate are as follows: I

A. Spreading the composition on the substrate by means of a spiral filmspreader; or

Spreading the composition on the substrate by means of a blade filmspreader.

B. Immersion of the substrate into the composition.

C. Use of a spray-gun.

D. Application by means of spreading rollers.

Depending on the spreading method used, coating compositions having different viscosities may be used.

Once a coating composition according to the invention has been applied to the substrate, it is then subjected to thermal treatment in an oven.-

Advantageous results are obtained with the coating compositions of the invention, when the thermal treatment is effected at temperatures between about 260 and 300C for from 1 to 2 minutes.

As a result of this thermal treatment, the latent and fluidizing solvents evaporate and the polymeric material deposits on the substrate in the form of a continuous and homogeneous film that is perfectly adherent, even after natural or artificial aging, after indenting, bending and boiling.

The coating films obtained by thermal treatment of the compositions according to the invention, are subjected to a series of tests for evaluating the following characteristics:

adherence hardness bending resistance cupping strength in an Erichsen Model 225 D impact resistance a melting point of about 220C. The copolymers were in the form of powders having an average particle size of 0.4 micron, both copolymers having a melt-flow-index value (according to ASTM 1238,

brightness 6ST) at 300C, load 3160 g, equal to 0.5. resistance 9 aging; agmgl 2. Dibutylphthalate.

an clrculatmg oven at 150C; 3. A commercial product known as Cellosolve and Water heated to 70C; consisting of C H O-CH -CH OH (monoethylc. in an artificial weather aging machine (Weather ether of ethylene glycol) was used Ometer) with a carbon are; 10 B. For comparative purposes, another coating comin a salty ebulation chamber (35C; 5% Nac] position was prepared exclusively based on a copolysfmmon mer containing 55 mol of tetrafluoroethylene. e. in a humido static chamber at 40C and 100% rel- For this purpose, a mixture consisting of the copoly humlfjltyi and mer, the same latent solvent and the same fluidizing by lmmerslon of a coated metallic Sample having solvent in the same weight ratios used in case (A) was a squared grid in boiling water and bending of the prepared in a ball mm squaljed Zone- C. For comparative purposes, and following the same The coating compositions of the invention after the procedures adopted in (A) and (B) above a third coat above described thermal treatment, result in coating ing composition exclusively based on a copolymer films generally endowed with good adhering charactertaining 41 mol of tetrafluoroethylene was prepared istics, even after the various aging treatments described compositions (A), (B) and (C) were applied Onto above. The bending resistance and the impact resisthree different meta] Substrates using a Spiral tance also good and remain so even after the Vari' spreader (No. 36). The three substrates were: 0.5 0.8 (ms agmgs mm thick sheets of aluminum, bright steel and chr0- The following examples are given to further illustrate mated aluminum (a commercial product known as the invention without, however, being a limitation Bonder AL 20 trademark of M ome catini Edison thereof. All parts are by weight unless otherwise indi- S p A Italy) Gated Compositions (A), (B) and (C) were filmed in an EXAMPLE 1 oven at 300C, for 2 minutes. After this thermal treat- A Coating composition was prepared by mixing in ment all the specimens (sheets) treated with (A) and a ban min for (C) appeared perfectly coated; on the contrary, a high percentage (70-80%) of those specimens that were treated with (B) showed conspicuous faults (shrinko1 mers (1 100 arts ages flaws cracks em) latent solvpemya) 225 g Some of the characteristics of the coating films are fluidizing solvent (3) 35 parts summarized in Table I.

These characteristics on the whole are quite satisfac- 1. A mechanical mixture of copolymers s used tory for all three compositions. It should be noted howconsisting of 90 parts of a copolymer containing 55 ever, that the coating films of composition (C), based mol of tetrafluoroethylene and having a melting on a o olymer having a tetrafluoroethylene content Point of about 275C (determined y differential below mol show a reduced resistance to chemical thermal analysis) and 10 parts of a copolymer conagents and atmospheric attacks. This is in accordance taining 41 mol of tetrafluoroethylene and having with the data reported in application Ser. No. 142,357. TABLE I Characteristics Of The Films Com- Substrate Film Adherlmpact Hard- Resistance to Resistance to Bending Resistance in posit- Thickness ence resistance ness Bending and boiling Water bath at ion C residual adherance Aluminum 15 microns 10 (unaltered) 2H unaltered OT 100% unaltered Bright 15 microns 100% 10 (unaltered) 2H unaltered OT none unaltered steel (A) Chromium plated 15 microns 100% 10 (unaltered) 2H unaltered OT 100% unaltered Aluminum Aluminum 15 microns 100% 10 (unaltered) 2H unaltered OT 100% unaltered Bright 15 microns 100% 10 (unaltered) 2H unaltered OT none unaltered steel (B) Chromium plated 15 microns 100% 10 (unaltered) 2H unaltered OT 100% unaltered Aluminum Aluminum 15 microns 100% 10 (unaltered) 2H unaltered OT none unaltered Bright 15 microns 100% 10 (unaltered) 2H unaltered OT 100% unaltered steel (C) Chromium plated 15 microns 100% 10 (unaltered) 2H unaltered OT 100% unaltered Aluminum FOOTNOTES TO TABLE I:

( l Determined according to the Gardner-Paint Test, Munualphysicul and Chemical Examination-Paint, Vumishes, Lacquers and Colors. Xll edition March 1962 Published by Gardner Laboratory Inc. USA A page 160; test of the orthogonal grid, square 1 mm; square number 10 X 10v (2) Determined according to the above cited Gardner-Paint test, page 147; head 1 kg.. diameter 16 mm; height of full 100 cm; evaluation scale: 10 unaltered; 6

= light cracks; 3 evident cracks and 0 complete detachment.

(3) Determined according to the above cited Gardner test. on page 131, modified in order to also check the compactness of the film according to the ECCA (European Coil Coating Association) method No. 6.

(4) (a) Determined according to the above mentioned Gardner-Test, page (h) according to the ECCA-method N" 7v (5) Determined according to the test described above on page 9, point f).

(6) Dctennined 0n the basis of the a earance of bubbles on the surfaces of the coating, and on the basis of variations in the degree of adherencev EXAMPLE 2 Two coating compositions were prepared by mixing, in a ball mill, for 24 hours:

parts of a copolymer containing 55 mol of tetrafluoroethylene was used.

These two compositions were filmed at varying temperatures and for varying times of thermal treatment.

Different types of metal substrates were coated with an E-TFE (A) or (B) copolymer mixture 100 parts iti n a latent solvent (dibutylphthalate) 225 parts each compos '0 a fluidizing solvent (methylethylke'tone) 35 parts All the specimens used were coated with homogeneous films having a thickness between and mi- A. A mixture consisting of 90 parts of a copolymer crons. containing mol of tetrafluoroethylene, and 10 10 The results obtained for some mechanical and physiparts of a copolymer containing 41 mol of tetrafluorcal tests are recorded in Tables II and Ill. oethylene was used. The tests relating to the resistance characteristics in B. A mixture consisting of parts of a copolymer a salty nebulation chamber are recorded in Tables IV containing 41 mol of tetrafluoroethylene and 10 and V. i

TABLE I1 Coating Characteristics Obtained with mix A (Example 2) Filming conditions 280C; 280C 290C; 300C; 300C; Substrate temperature and time 90 seconds 120 seconds 90 seconds 120 seconds 90 Seconds 120 seconds "/1 Adherence after none l00% 100% 100% 100% Aluminum bending and boiling none none none none none none Bright in H2O for 30 minutes l steel Resistance to bending I T l T l T l T l T l T Aluminum and Bright steel Pencil hardness H H H H H H Aluminum and Bright Steel (a) Test carried out with a conical mandrel according to the Gardner-Paint Test Xll Edition (1962) (Publisher Gardner Laboratory Inc. USA). page 140 TABLE III Coating Characteristics Obtained with mix B (Example 2) Filming conditions 270C; 270C; I 280C; 280C; 290C; 290C; 300C; 300C; Substrate temperature and time 90 90 120 90 120 90 120 seconds seconds seconds seconds seconds seconds seconds seconds Adherence after none none none none none none none none Aluminum bending and boiling none 100% 80% 100% 100% 100% 100% 100% Bright in H O for 30 minutes steel Resistance to bending (a) l T l T l T l T O T O T O T O T Aluminum 0 T O T 1 T 1 T l T I T V I T l T Bright steel Pencil hardness H H H H H H H H Aluminum and Bright steel (a) See note to Table II.

TABLE IV Resistance Characteristics of Coatings Obtained with mixes of type (A) (see Example 2) Type of Thermal treatment Thickness of the Erichsen Shock- Resistance in saline Substrate (filming) film in microns drawing resistance mist (3) seconds test l (2) Bubbles Rust Aluminum 90 280v 13 15 7.3 excellent absent absent I20 280 13 15 7.5 90 290 16 18 7.5 120 290 18 20 7.2 90 300 18 20 7.8 I20 300 13 15 7.6 Iron 90 280 15 17 10 6M 30 120 280 I3 15 10 5-6M 3O 90 290 15 l8 l0 6M 30 120 290 16 I8 10 4-5M 30 90 300 13 15 I0 SM-D 3O 120 300 14 16 10 5-6M 30 Phosphatated iron 120 280 15 l8 l0 9F 10 I20 290 16-18 10 8F I 5 120 300 16 -18 l0 8F 5 (l) Determined on an Erichslen apparatus Model 225D.

(2) See note to Table l. (3) Duration of test: 300 hours.

(4) This datum indicates the'percentage of the surface of the specimen attacked by rust.

TABLE V Resistance Characteristics of the Coatings Obtained with the mixes of Type (B) (see Example 2) Type of Thermal treatment Thickness of the Erichsen Impact Resistance to saline substrate (filming) film in microns drawing Resistance mist (3) seconds C test (1) (2) Bubbles Rust (4) Aluminum 120 270 15 18 7.5 excellent absent absent 90 300 18 20 7.2 120 300 18 20 6.4 Iron 90 270 I8 20 10 5M 40 120 270 15 l8 l -6F 40 90 280 18 20 10 6M-D 50 120 280 16 -18 1O 5M 40 90 300 18 20 9.7 5M 40 I20 300 16 9.5 6-7M 40 Phosphatated iron 120 270 15 16 1O 8D 30% 8 120 280 18 20 10 7F 8 120 300 14 16 9.7 7M 10 (l) Determined on an Erichsen apparatus Model 225D. [2) See note to Table l. (3) Duration of test: 300 hours.

{4) This datum indicates the percentage of the surface of the specimen attacked by rust.

EXAMPLE 3 A coating composition was prepared using a two-step process comprising first dispersing the various components set forth below in a Cowles stirrer and subsequently grinding the resultant mass in a ball mill for 24 hours.

The recipe for the composition was as follows:

E-TFE copolymers l) 40 parts dimethylphthalate 120 parts dibutylphthalate 9 parts isophorone 8 parts toluene 1 part butyrolactone 2 parts l A mechanical mixture consisting of 20 parts of a copolymer containing 41 mol of tetrafluoroethylene and 20 parts of a copolymer containing 55 mol of tetrafluoroethylene.

note 4 of Table 1) was OT and the coatings remained 50 3 unchanged. The bending resistance as described in footnote 5 of Table I, amounted to 100%. The hardness, measured with a pencil, was 2H for the steel substrates and F for the chromate treated substrates.

EXAMPLE 4 Example 3 was repeated, except that as the E-TFE copolymers, mechanical mixtures were used as follows:

copolymer having 55 mol of tetra fluoroethylene 90 50 20 copolymer having 68 mol of tetra fluoroethylene with a melting point of about 250C 10 50 80 The resistance to weather aging, after many thousands of hours of outside exposure was definitely more marked than that which was observed for the compositions of Example 3.

Variations can, of course, be made without departing from the spirit and scope of the invention.

Having thus described our invention, what we desire to secure by Letters Patent and hereby claim is:

l. A coating composition comprising an ethylenetetrafluoroethylene copolymer mixture and at least one latent solvent, said ethylene-tetrafluoroethylene copolymer mixture being constituted by a. 10-90% of at least one ethylene-tetrafluoroethylene copolymer having a melting point from about 250 to about 315C. and containing between 52 and 58 mol of chemically combined tetrafluoroethylene, and

b. 90-10% of at least one ethylene-tetrafluoroethylene copolymer having a melting point from about 180 to about 285C. and containing from 35 to 45 mol of chemically combined tetrafluoroethylene.

2. A coating composition according to claim 1, and being capable of undergoing film formation upon being heated at a temperature between 260 and 300C, for between 1 and 2 minutes.

A coating composition according to claim 1, and further comprising at least one fluidizing solvent.

4. A coating composition according to claim 1, and further comprising at least one pigment.

5. A coating composition according to claim 3, and further comprising at least one pigment.

6. A coating composition according to claim 1, and further comprising at least one inert tiller.

7. A coating composition according to claim 3, and

60 further comprising at least one inert filler.

8. A coating composition according to claim 1, and further comprising at least one additive selected from the group consisting of surfactants, stabilizers, antioxidants and ultraviolet absorbers.

UNITED STATES PATENT OFFICE CERTIFICATE OF CORRECTION Patent No. 3,906,060 Dated September 16, 1975 Inventor(s) Andrea MATTIIUSSI and Mario MODENA Page 2 It is certified that error appears in the above-identified patent and that said Letters Patent are hereby corrected as shown below:

Columns 9-10, the heading of Table V, column 5:

. "Impact should read Impact Resistance Resistance Engncd and Scaled thus sixth D y of January 1976 [SEAL] Attest:

RUTH C. MASON c MARSHALL DANN Arresting Officer Commissioner ufPaie/ns and Trademarks 

1. A COATING COMPOSITION COMPRISING AN ETHYLENETETRAFLUOROETHYLENE COPOLYMER MIXTURE AND AT LEAST ONE LATENT SOLVENT, SAID ETHYLENE-TETRAFLUOROETHYLENE COPOLYMER MIXTURE BEING CONSTITUTED BY A. 10-90% OF AT LEAST ONE ETHYLENE-TETRAFLUOROETHYLENE COPOLYMER HAVING A MELTING POINT FROM ABOUT 250* TO ABOUT 315*C. AND CONTAINING BETWEEN 52 AND 58 MOL % OF CHEMICALLY COMBINED TETRAFLUOROETHYLENE, AND B. 90-10% OF AT LEAST ONE ETHYLENE-TETRAFLUOROETHYLENE COPOLYMER HAVING A MELTING POINT FROM ABOUT 180* TO ABOUT 285*C. AND CONTAINING FROM 35 TO 45 MOL % OF CHEMICALLY COMBINED TETRAFLUOROETHYLENE.
 2. A coating composition according to claim 1, and being capable of undergoing film formation upon being heated at a temperature between 260* and 300*C., for between 1 and 2 minutes.
 3. A coating composition according to claim 1, and further comprising at least one fluidizing solvent.
 4. A coating composition according to claim 1, and further comprising at least one pigment.
 5. A coating composition according to claim 3, and further comprising at least one pigment.
 6. A coating composition according to claim 1, and further comprising at least one inert filler.
 7. A coating composition according to claim 3, and further comprising at least one inert filler.
 8. A coating composition according to claim 1, and further comprising at least one additive selected from the group consisting of surfactants, stabilizers, anti-oxidants and ultraviolet absorbers.
 9. A coating composition according to claim 3, and further comprising at least one additive selected from the group consisting of surfactants, stabilizers, anti-oxidants and ultraviolet absorbers. 